2013
DOI: 10.1039/c2nr32629a
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Graphene synthesis: relationship to applications

Abstract: Graphene is a true wonder material that promises much in a variety of applications that include electronic devices, supercapacitors, batteries, composites, flexible transparent displays and sensors. This review highlights the different methods available for the synthesis of graphene and discusses the viability and practicalities of using the materials produced via these methods for different graphene-based applications.

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Cited by 659 publications
(384 citation statements)
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“…35,36 Reacting graphite with strong acid (H 2 SO 4 ) and strong oxidant (KMnO 4 ), known as the modified Hummers method, is another common method used to obtain predominantly stage 1 GIC. 37 In the graphite bisulphate, the graphite structure remains mainly intact because the guest molecules are only located in between the carbon layers, whereas chemical intercalation with a strong oxidant negatively affects the graphite's electronic properties as its conjugated sp 2 structure is disrupted. Intercalation is also possible using milder conditions through co-intercalation with iron chloride (FeCl 3 ) and nitromethane (CH 3 NO 2 ).…”
Section: Graphitementioning
confidence: 99%
“…35,36 Reacting graphite with strong acid (H 2 SO 4 ) and strong oxidant (KMnO 4 ), known as the modified Hummers method, is another common method used to obtain predominantly stage 1 GIC. 37 In the graphite bisulphate, the graphite structure remains mainly intact because the guest molecules are only located in between the carbon layers, whereas chemical intercalation with a strong oxidant negatively affects the graphite's electronic properties as its conjugated sp 2 structure is disrupted. Intercalation is also possible using milder conditions through co-intercalation with iron chloride (FeCl 3 ) and nitromethane (CH 3 NO 2 ).…”
Section: Graphitementioning
confidence: 99%
“…of graphene layers and to be able to separate these layers into individual sheets of graphene, van der Waals forces need to be overcome [13]. This approach is referred to as the top-down approach.…”
Section: Synthesis Of Graphenementioning
confidence: 99%
“…Several challenges are associated with this approach, like surface defects that occur during sheet separation and the separated sheets reagglomerating afterwards. In general, the top-down approaches offer low yields and are tedious procedures [13]. While the top-down approach focuses on breaking graphene precursor (graphite) into atomic layers from a stack (Fig.…”
Section: Synthesis Of Graphenementioning
confidence: 99%
“…In the top-down approach, layers of graphite are simply separated to get the graphene layer. But to do this, van der waals interaction between the layers need to be broken [8]. However, there are several challenges with this method such as defects in the surfaces may occur during the preparation of sheets of graphene and the discrete sheets cumulate subsequently.…”
Section: Introductionmentioning
confidence: 99%
“…However, there are several challenges with this method such as defects in the surfaces may occur during the preparation of sheets of graphene and the discrete sheets cumulate subsequently. Generally, the top-down approach offers low yield and the process is very tedious [8]. In the bottom-up approach, carbon molecules which are procured from different origins are used as building blocks [9].…”
Section: Introductionmentioning
confidence: 99%