Utilization of graphene (GE) in water
is physically limited by
its lack of functional groups, high hydrophobicity, and large interlayer
van der Waals forces. Easy agglomeration of GE makes the preparation
of GE-filled composites in an aqueous environment very difficult.
Conventional methods solve this problem by introducing a surfactant
to the system. However, the addition of a large amount of surfactant
may hinder the performance of the composite. In this study, highly
stable GE aqueous suspensions (remaining stable for more than 30 days)
with a high concentration (1.5 mg/mL) were conveniently prepared by
using graphene oxide (GO) as a stabilizer. A GE- and GO-filled rubber
composite prepared by this GO–GE water suspension in an aqueous
environment was also prepared and analyzed. It was found that a dual-network
with dual functions was formed in the composite matrix: the GE network
enhanced the electrical conductivity of the composite, while the GO
network enhanced its mechanical properties. Our method is green, simple,
and highly efficient, providing an alternative to improve GE’s
dispersion in water and synthesize GE-filled composites in an aqueous
environment.