2014
DOI: 10.3144/expresspolymlett.2014.60
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Graphene modified electrospun poly(vinyl alcohol) nanofibrous membranes for glucose oxidase immobilization

Abstract: Abstract. In this study, poly(vinyl alcohol) (PVA)/Glucose oxidase (GOx)/graphene biocomposite membranes were prepared using an electrospinning technique and used for enzyme immobilization. The PVA/GOx/graphene membrane's morphology was examined by scanning electron microscopy (SEM) and transmission electron microscopy (TEM), while its electrochemical sensitivity was studied by chronoamperometry. Kinetic parameters were determined to clarify the role of graphene in enzyme immobilization, while a spectrophotome… Show more

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Cited by 30 publications
(21 citation statements)
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“…The superior performance of the electrospun fiber membrane when compared to casted film membranes was explained by the increase in porosity and surface area. A similar glucose sensor was fabricated by direct deposition of electrospun PVA/glucose oxidase/GO membrane onto the platinum electrode, in which PVA nanofibers were cross‐linked with glutaraldehyde . The presence of graphene helped to stabilize the enzyme's conformation, facilitated the catalytic reactions, and increased the survivability of the enzyme.…”
Section: Graphene Assemblies For Biosensorsmentioning
confidence: 99%
“…The superior performance of the electrospun fiber membrane when compared to casted film membranes was explained by the increase in porosity and surface area. A similar glucose sensor was fabricated by direct deposition of electrospun PVA/glucose oxidase/GO membrane onto the platinum electrode, in which PVA nanofibers were cross‐linked with glutaraldehyde . The presence of graphene helped to stabilize the enzyme's conformation, facilitated the catalytic reactions, and increased the survivability of the enzyme.…”
Section: Graphene Assemblies For Biosensorsmentioning
confidence: 99%
“…In addition, graphene, a new generation carbonaceous-layered material has shown considerable potential as a reinforcing material in polymer nanocomposites. It has a very large surface area and tunable surface properties [109][110][111][112][113][114].…”
Section: Future Challenges and Conclusion Remarksmentioning
confidence: 99%
“…36 Wu also investigated the ampere response by electrochemical analysis. When the addition amount of graphene was increased to 20 ppm, the composite nanofibers showed the shortest response time (9.90 s) and sensitivity of 38.70 mA/mM.…”
Section: Polarization Curve and Power Densitymentioning
confidence: 99%