Grain Boundary Complexions and Phase Transformations in Al- and Cu-Based Alloys

Abstract

High-pressure torsion has been used to obtain the ultra-fine grained (UFG) state with a high specific area of grain boundaries (GBs) in Al-Zn, Al-Mg, Cu-Ag, Cu-Co, and Cu-Ni solid solutions with face-centered cubic (fcc) lattices. The UFG samples were heated in a differential scanning calorimeter (DSC). Small endothermic peaks in the DSC curves were observed in the one-phase solid-solution area of the respective phase diagrams, i.e., far away from the bulk solidus and solvus lines. A possible explanation of these endothermic peaks is based on the hypothesis of phase transformations between GB complexions. This hypothesis has been supported by observations with transmission electron microscopy and electron backscattering diffraction. The new lines of GB phase transformations have been constructed in the Al-Zn, Al-Mg, Cu-Ag, Cu-Co, and Cu-Ni bulk phase diagrams.

Phase Transformations in the AlMg Alloys Driven by High‐Pressure Torsion

“…Recently, the authors studied the samples of the Al–10 wt% Mg alloy in the single‐phase region of AlMg phase diagram after SPD by high‐pressure torsion (HPT). [ 39 ] In this work, it was shown that such compounds as metastable phases appear after HPT in the single‐phase region of the (Al) solid solution. On the contrary, other authors [ 40–43 ] found the metastable phases in the single‐phase region of AlMg alloys.…”

Alloying Element Segregation and Grain Boundary Reconstruction, Atomistic Modeling

“…It is commonly believed that such broad segregations may belong to a special so-called non-equilibrium structure of a GB [2,3]. Other mechanism of the formation of such broad enriched regions is recently discussed in connection with the segregation induced GB structural transitions [14,[26][27][28][29][30][31].…”