Grafting of polyacrylonitrile to granular corn starch by initiation with cerium

Brockway, C. E.; Seaberg, P. A.

doi:10.1002/pol.1967.150051129

Cited by 4 publications

(2 citation statements)

References 11 publications

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“…Nonlinear polymer architectures, such as bottlebrush polymers, have been synthesized for decades going back to the 1950s. − Synthesis of these highly grafted polymers have evolved from using naturally obtained macromolecules as backbones ,,,− or incorporating oligosaccharide side chains, − to using synthetic monomers entirely . Synthetic advances in controlled/living polymerization techniques have simplified the synthesis of advanced architectures like bottlebrush polymers.…”

Section: The Basics Of Bottlebrush Polymersa Historical Viewmentioning

confidence: 99%

Materials Design of Highly Branched Bottlebrush Polymers at the Intersection of Modeling, Synthesis, Processing, and Characterization

et al. 2022

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Highly branched “bottlebrush” polymers are a class of macromolecules characterized by side chains that are densely grafted from a backbone that is typically linear. Their unique and often-desirable properties stem from steric repulsion between side chains, which stiffens the molecular contour and increases interchain spacing. There has been a renaissance in both our fundamental understanding, practical synthesis, and application of these materials, due to synergistic advances in all branches of polymer science. In this perspective, we outline how a wide variety of new functional bottlebrush materials have emerged from the convergence of insights from the entire materials design process; the integration of synthesis, characterization, processing, and modeling has demonstrated the promise of these branched macromolecules as a versatile platform for molecular engineering. We discuss how this platform may be further developed to exhibit novel material properties in and out of equilibrium and put into practice due to the next generation of synthetic, analytical, processing, and computational tools in materials chemistry.

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Section: The Basics Of Bottlebrush Polymersa Historical Viewmentioning

confidence: 99%

Materials Design of Highly Branched Bottlebrush Polymers at the Intersection of Modeling, Synthesis, Processing, and Characterization

et al. 2022

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“…Cerium salts have been used as initiators in gra polymerization. [57][58][59] Fig. 4 shows the process of radical production of starch by using cerium salt as an initiator.…”

Section: Starch-gra-copolymermentioning

confidence: 99%

Recent progress in chemical modification of starch and its applications

et al. 2015

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Starch has received much attention as a promising natural material both in biomedical fields and waste water treatment due to its unique biological and adsorptive properties. Recently, the modification of starch is rapidly developed along with its growing applications. This review focuses on the ways of chemical modification of starch including cross-linking, grafting, esterification, etherification, dual modification and so on, and presents the applications of the modified starch in fields like drug delivery, tissue engineering and heavy metal and dye removal.

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