1990
DOI: 10.1039/dt9900002185
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Gold–boron chemistry. Part 2. The interaction of {AuP(C6H11)3} bridges with decaboranyl cages: the accurate structure of [5,6-µ-{AuP(C6H11)3}-nido-B10H13], and the synthesis and molecular and electronic structures of its conjugate base [5,6,9,10-µ4-{AuP(C6H11)3}-nido-B10H12]

Abstract: Analysis of the results of an accurate, low-temperature redetermination of the molecular structure of [5,6-p-{Au~(C6H,l),)-nido-~,oH13] (1 a) implies an interaction, albeit weak, between the bridging gold atom and the B(9)H(9,1 O)B(lO) moiety, and extended Huckel molecular orbital (EHMO) calculations reveal that the nature of this bonding is interaction of the three-centre twoelectron-B (9) H B (1 0) unit with a previously vacant 6sp-hybrid orbital on gold. Mossbauer parameters obtained for ( l a ) are consist… Show more

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Cited by 9 publications
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