Glass Fillers in Three Different Forms Used as Reinforcement Agents of Polylactic Acid in Material Extrusion Additive Manufacturing

Abstract

The industrial demand for functional filaments made of bio-sourced, biocompatible, biodegradable, and/or recyclable polymers and composites for material extrusion (MEX) 3D printing is continuously growing. Polylactic acid (PLA), the most popular filament, combines such properties, yet its reinforcement with low-cost, inert, and/or recycled fillers remains challenging. Herein, glass in three different micro/nano-forms was the reinforcement agent in PLA. Three different experimental tiers were elaborated by producing composite filaments with glass in powder, beads, and flake forms in various loadings to optimize the concentrations. A thermomechanical process, i.e., melt filament extrusion, was exploited. The composites were evaluated for their thermal degradation stability and composition using thermogravimetric analysis and Raman. MEX 3D printing was used to produce tensile, flexural, impact, and microhardness specimens, to quantitatively evaluate their mechanical response. Field emission scanning electron microscopy evaluation and fractography were carried out to depict fracture patterns of the specimens after their tests. All three glass types induced impressive reinforcement effects (up to 60% in flexural loading), especially in the flake form. The impact of the additional process cost through glass fillers implementation was also assessed, indicating that such composites are cost-effective.

The Effect of Nano Zirconium Dioxide (ZrO2)-Optimized Content in Polyamide 12 (PA12) and Polylactic Acid (PLA) Matrices on Their Thermomechanical Response in 3D Printing

“…Some examples of 3DP AM technologies include binder jetting (material jetting), selective laser sintering (powder bed fusion), stereolithography, digital light processing (vat photopolymerization), and Fused Filament Fabrication (FFF) (material extrusion—MEX) [ 32 ]. Among them, FFF is commonly used for manufacturing thermoplastic polymeric material components and polymer compounds, such as nano compounds and fiber-reinforced composites [ 32 , 33 , 34 , 35 , 36 , 37 , 38 ]. Although significant progress has been made in 3D printing accuracy, automation, and printer parts, such as nozzles and heatable beds, which can affect final part quality [ 39 ], research on thermoplastic materials with enhanced mechanical, thermal, electrical, and magnetic properties in comparison to pure polymers is ongoing to create multi-functional printed objects [ 40 ].…”