2007
DOI: 10.1002/adma.200600703
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Giant Dielectric Permittivities in Functionalized Carbon‐Nanotube/ Electroactive‐Polymer Nanocomposites

Abstract: Trifluorophenyl‐functionalized multi‐walled‐carbon‐nanotube/poly(vinylidene fluoride) (TFP‐MWNT/PVDF) nanocomposites are fabricated by employing a wet‐chemistry route. The modified MWNTs are observed to form a well‐dispersed, structurally random nanophase within the polymer matrix (see figure). The TFP‐MWNT/PVDF nanocomposite exhibits enhanced dielectric permittivity when the content of TFP‐MWNT is close to the percolation threshold.

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Cited by 777 publications
(642 citation statements)
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“…These conductive particles are associated with induced internal fields which neutralizes the external applied field, thus making their corresponding composites good dielectric material compared with their unfilled counterparts (Akram et al 2005;Sutton, 1956). Nevertheless, the lower in ε´at high frequency is a common phenomenon associated with inability of the electrical field to cope with the oscillating filed (Dang et al 2007).…”
Section: Dielectric Constant Propertymentioning
confidence: 99%
“…These conductive particles are associated with induced internal fields which neutralizes the external applied field, thus making their corresponding composites good dielectric material compared with their unfilled counterparts (Akram et al 2005;Sutton, 1956). Nevertheless, the lower in ε´at high frequency is a common phenomenon associated with inability of the electrical field to cope with the oscillating filed (Dang et al 2007).…”
Section: Dielectric Constant Propertymentioning
confidence: 99%
“…However, the potential of CNTs to serve as conductive filler is partially eclipsed due to the strong inter-filler force that leads to aggregation of CNTs and the poor interface between CNT and polymer. To better disperse the CNTs and subsequently obtain superior electrical properties of CNT/polymer composites, researchers like Dang et al (2007b) and Liu et al (2011) Liu et al (2011) where, despite the chemical modification of CNTs, the dielectric permittivity of the composites was below 100 even at the CNT concentration of 20 vol. %.…”
Section: Introductionmentioning
confidence: 99%
“…They are: System I -(PANI-PVDF), 26 System II -(CB-BT-VMQ), 30 System III -(Ag-PI), 31 System IV -(CF-PVDF), 32 System V -(TFP-MWNT-PVDF), 33 and System VI -(MWNT-PVDF). 34 The first three systems use a spherical filler, while the last three use one-dimensional filler particles.…”
Section: Experimental Methodsmentioning
confidence: 99%