“…The presence of faults and fractures in seals, even if they cause only a minor enhancement of seal permeability prior to CO 2 injection, implies that models that describe the seals as homogeneous may underestimate the sensitivity of k v and P c,b to geochemical and geomechanical alteration. ,,,,,,− Three lines of evidence indicate that clays and clay minerals play an important role in this sensitivity. First, conventional hydrocarbon exploration studies have found that, despite the structural and petrophysical complexity of faults, ,,, the barrier properties of faults are primarily determined by the clay content of the fault-filling material as quantified by proxies such as the shale gouge ratio (SGR). ,− With increasing clay content or SGR, fault permeability decreases from ∼10 –15 to 10 –19 m 2 and P c,b increases from ∼0.1 to 10 MPa. , Second, the fault friction coefficient μ s of the Mohr–Coulomb failure model, an important parameter in the brittle failure of rocks and the mechanics of slip along faults and fractures, ,,,− depends strongly on clay content: μ s values range from 0.6 to 0.85 for most rocks, ,, but clay-rich rocks can have μ s values as low as 0.2. ,,,,− Clay-rich rocks also tend to deform in a more ductile, self-sealing manner than other rocks, a desirable seal property. ,,,, Finally, the stress-porosity-permeability relations of porous media (or stress-aperture-permeability, in the case of unfilled fractures), of key importance in predicting the permeability of preferential flow paths in seals, ,,, are highly sensitive to clay content. ,, For example, the permeability k of sedimentary rocks is routinely modeled as having a power-law dependence on porosity ϕ, where n ∼ 3 in homogeneous, nonclayey media and larger n values are associated with emergent phenomena such as wormhole-like or bedding-oriented dissolution paterns ,<...…”