Soil development and soil formation processes are often considered to take long periods of time from hundreds to millions of years. This thesis investigates the potential for land use change to drive whole soil profile development processes in unexpected ways and at unexpected speeds in Eastern Australia. The major objectives of this thesis were to identify and document locations where rapid soil profile changes occur at a land use boundary, to investigate the nature of soil changes across that boundary and propose mechanisms for observed changes. Alternating arid and humid phases in the Quaternary, coupled with contemporary Holocene and Anthropocene sub-decadal climate variability, makes availability of soil water in Eastern Australia a critical driver to soil development processes. In contrast, many northern climates are constant or at least seasonal and moist. An initial study (Chapter 3) was undertaken using archival soil survey data from the Liverpool Plains region in the northwest slopes and plains of New South Wales (NSW). The desktop study examined key soil fertility properties in relation to land use through an historical soil survey dataset to determine whether large-scale European land use impacts on whole soil profiles could be observed. Land uses compared were cropping, native pasture, improved pasture and woodland. Soil type, land use, and soil × land use were considered in a mixed model restricted maximum likelihood (REML) analysis using general fertility attributes of available water holding capacity (AWC), soil phosphorus (Bray P), cation exchange capacity (CEC), dispersion percentage (DP), salinity (ECe), sodicity (indicated by exchangeable sodium percentage, ESP) and soil pH. Results showed that fertility attribute variation depended on soil type reflecting land selection for agriculture. Soil organic carbon (SOC) values were considered a product of fertility but were most strongly associated with land use with SOC being lowest in cropping regardless of soil type. This approach did not illuminate any maninduced whole soil profile changes. General soil survey data was found to be potentially limited by the method of land use and site history recording. The second study (Chapters 4 and 5) investigated physical and chemical soil profile changes associated with managed tropical pastures compared with volunteer native pastures on sodic-duplex soils in northwestern NSW. These soils are limited by low fertility topsoils, poor soil profile drainage and clay-rich B horizons which native vegetation roots and soil water do not readily penetrate. Results indicated that deeper, more abundant tropical pasture roots had initiated changes in soil profile porosity, structure and chemistry. Macroporosity (pores > 30µm) of critical infiltration and root v Publications included in this thesis No publications included.