2005
DOI: 10.1177/0734904105047006
|View full text |Cite
|
Sign up to set email alerts
|

GC/MS Identification of Pyrolysis Products from Fire-retardant Brominated Epoxy Resin

Abstract: Brominated epoxy resins cured with diaminodiphenyl sulfone are thermally less stable than nonbrominated analogs. This thermal instability is likely to be caused by the formation of hydrogen bromide which destabilizes the epoxy network. As a result of the reaction of HBr with the epoxy resin, brominecontaining aromatics (brominated phenols, alkenyl aryl ether, hydroxyalkyl aryl ethers), as well as nonbromine-containing compounds form high-boiling decomposition products. The mass spectra of the brominated produc… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
2
1
1
1

Citation Types

2
12
0

Year Published

2007
2007
2024
2024

Publication Types

Select...
8

Relationship

0
8

Authors

Journals

citations
Cited by 24 publications
(14 citation statements)
references
References 26 publications
2
12
0
Order By: Relevance
“…Bromoacetone attribution was confirmed from SDBS spectral database of organic compounds [15] and in [16]; MS spectrum attributed to tribromobisphenol A corresponds to that reported by Blazsó [16] and that of dibromo(methyl ethenyl) phenol to that reported in Ref. [17]. Pyrogram at 500 • C of DGETBBA shows similar features but a lower extent of degradation.…”
Section: Pyrolysis Experimentssupporting
confidence: 54%
See 1 more Smart Citation
“…Bromoacetone attribution was confirmed from SDBS spectral database of organic compounds [15] and in [16]; MS spectrum attributed to tribromobisphenol A corresponds to that reported by Blazsó [16] and that of dibromo(methyl ethenyl) phenol to that reported in Ref. [17]. Pyrogram at 500 • C of DGETBBA shows similar features but a lower extent of degradation.…”
Section: Pyrolysis Experimentssupporting
confidence: 54%
“…2, all others compounds have been identified by current MS libraries with high score value (>91) and by published MS spectra [14][15][16][17]; for instance MS spectrum of DGEBA closely matches reference no. 134714 in Wiley MS library.…”
Section: Pyrolysis Experimentsmentioning
confidence: 99%
“…These polymeric fire retardants included tribromoneopentyl alcohol [26,27], phosphoric acid 3-(diphenoxy-phosphoryloxy)-phenyl ester diphenyl ester [28][29][30], chlorinated paraffin with 65% chlorine content [31][32][33][34] and tetrabromobisphenol A bis (2,3-dibromopropyl ether) [35,36], which is also known to possess biocide functionality [37].…”
Section: Polymeric Fire Retardants Used In This Workmentioning
confidence: 99%
“…Balabanovich et al [54] undertook detailed analysis of the products formed from the thermal degradation of epoxy resin containing brominated fire retardants using thermogravimetry with gas chromatography/mass spectrometry.…”
Section: Presence Of Brominated Compounds In Pyrolysis Oils From the mentioning
confidence: 99%