2005
DOI: 10.1063/1.1883715
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Gate-refreshable nanowire chemical sensors

Abstract: ZnO nanowire field effect transistors were implemented as highly sensitive chemical sensors for detection of NO2 and NH3 at room temperature. Due to a Debye screening length comparable to the nanowire diameter, the electric field applied over the back gate electrode was found to significantly affect the sensitivity as it modulates the carrier concentration. A strong negative field was utilized to refresh the sensors by an electrodesorption mechanism. In addition, different chemisorbed species could be distingu… Show more

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Cited by 433 publications
(253 citation statements)
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“…Semiconductor Nanowires (NW) with novel functionalities have attracted great interest for electronic applications such as piezoelectronics energy conversion devices, 1-4 as well as sensors, [5][6][7][8][9] memory 10 and optical devices. [11][12][13][14][15][16] Among such systems, ZnO has always stood out due to its attractive wide band gap (3.37 eV at room temperature) with a high exciton binding energy (60 meV), which makes it appropriate for short wavelength optoelectronic applications, such as ultra-violet (UV) detectors, and UV and blue light emitting devices.…”
Section: Introductionmentioning
confidence: 99%
“…Semiconductor Nanowires (NW) with novel functionalities have attracted great interest for electronic applications such as piezoelectronics energy conversion devices, 1-4 as well as sensors, [5][6][7][8][9] memory 10 and optical devices. [11][12][13][14][15][16] Among such systems, ZnO has always stood out due to its attractive wide band gap (3.37 eV at room temperature) with a high exciton binding energy (60 meV), which makes it appropriate for short wavelength optoelectronic applications, such as ultra-violet (UV) detectors, and UV and blue light emitting devices.…”
Section: Introductionmentioning
confidence: 99%
“…More interest in nanotechnology is growing due to the novel properties of nanomaterials and their potentials for applications in many fields. For example, nanowires can be potentially used in nanophotonics, lasers (Zimmler et al, 2008), nanoelectronics (Javey et al, 2007), solar cells (Tsakalakos et al, 2007), resonators (Tanner et al, 2007) and sensors (Fan et al, 2005). They could also be used as catalysts (Haruta et al, 1993), functional coatings, in nanoelectronics (Garnett et al, 2007) and energy storage .…”
Section: Introductionmentioning
confidence: 99%
“…ZnO has a wide direct band gap, which coupled with the large exciton binding energy (60 meV), makes it a candidate for a variety of optoelectronic device applications such as light emitting diodes, lasers and UV photo-detectors [1,2]. ZnO gas sensors have also been demonstrated, with sensitivity to a range of vapours including alcohols, water vapour, ammonia and hydrogen [3,4,5,6,7,8]. The sensing mechanism common to semiconducting metal oxides, such as ZnO which is typically n-type due to oxygen vacancies and/or interstitial Zinc, involves the formation of a charge depletion layer on the surface due to electron trapping at adsorbed oxygen species [9,6].…”
Section: Introductionmentioning
confidence: 99%
“…Macro scale components and conventional manufacturing techniques cannot provide sensors that deliver the detection levels and low temperature operation increasingly required for future applications. For example thin-film metal oxide based gas sensors typically require heating to 200-400 • C. Hence, the move toward sensors fabricated from nanomaterials [10], such as metal oxide nanorods [3,4,5,7,8,6] that offer lower temperature operation and high-sensitivities due, primarily, to their high surface area to volume ratios.…”
Section: Introductionmentioning
confidence: 99%