Charge trapping characteristics of asymmetrical tunnel barriers consisting of different dielectric materials were investigated for application of nonvolatile memory devices. A thin HfO 2 layer stacked on ultrathin SiO 2 layer (SiO 2 /HfO 2 tunnel barrier) revealed higher current sensitivity to applied gate voltage than the conventional single SiO 2 tunnel barrier. On the other hand, the electron trapping of the tunnel barriers increased with the thickness of HfO 2 layer. Thus, a thin HfO 2 layer is promising for the engineered tunnel barriers, while a thick HfO 2 layer is appropriate for charge trapping layers for high-integrated nonvolatile memories. Meanwhile, an ultrathin Al 2 O 3 /HfO 2 tunnel barrier also revealed good electrical characteristics and is suitable for low temperature fabrication process.