“…In this paper, we present results of phase separation of a single‐component system of 1,2‐dihexadecanoyl‐ sn ‐glycero‐3‐phospho‐[ N ‐(4‐nitrobenz)‐2‐oxa‐1,3‐diazolyl]ethanolamine (DPPE‐NBD) in which a liquid‐condensed (LC) phase co‐exists with a liquid‐expanded (LE) phase (Ivanov et al ., 1997). Domain formation in the co‐existence region was studied using a newly developed combined scanning probe microscope (SPM) which permits the acquisition of some surface information, such as surface potentials, together with morphology by using a thin‐step etched optical fibre probe (Muramatsu et al ., 1997; Fujihira et al ., 1998; Muramatsu et al ., 1998).…”