The technique of combinatorial atmospheric pressure (AP)CVD, a recent addition to the growing number of combinatorial materials methods, is used to form twelve members of the Ti x V 1-x N alloy series with 0.29 < x < 0.94. This series of compounds has a rock-salt structure with TiN and VN as the end members. The twelve phases, which have potential use as heat mirror coatings, are all synthesized in a single experiment. The structure and properties of the materials are investigated using powder X-ray diffraction (XRD) and electron probe microanalysis (EPMA). The optical properties are considered using visible-IR spectroscopy (IRS), which allows the suitability of the films as solar control coatings to be investigated and optimized as a function of composition.