Self-powered solar-blind Ga2O3-based
photodetectors
based on polycrystalline films rather than single-crystal films have
been widely studied. In this work, Ta-doped Ga2O3 single-crystal films deposited on porous p-type GaN substrates by
metal–organic chemical vapor deposition (MOCVD) were prepared
as self-powered solar-blind photodetectors. As the porosity of the
substrate increased, the crystal quality of the deposited film was
optimized, probably resulting from the reduction of threading dislocations
(TDs). The epitaxial relation between the β-Ga2O3 single-crystal film and the GaN substrate was β-Ga2O3 (2̅01) || GaN (0001) with β-Ga2O3 [010] || GaN <21̅1̅0>. Compared
with the photodetector based on the β-Ga2O3 grown on as-grown p-GaN, the detector based on the β-Ga2O3 deposited on porous p-GaN presented fast rise/decay
times (0.41 s/0.34 s) and high photoelectric responsivity (3.54 ×
10–2 A/W) at 222 nm without bias because of the
electron–hole pairs separated by the in-built electric field
rapidly, indicating good solar-blind response ability.