Free radical chemistry. Part 5. [1] A new approach to the synthesis of perfluorinated ethers

Micro reactors: principles and applications in organic synthesis

“…In conventional reactions, cobalt tri¯uoride would be used to per¯uorinate hydrocarbons. 76 Some of the reactions carried out by the authors, however, required much lower temperatures than would be expected if this compound was used.…”

A New Approach to Highly Fluorinated Lubricants.

“…In earlier work from this laboratory, we have demonstrated the value of perfluoroalkyl groups being present. 7 In this way, xrious perfluoroethers were characterised, thus demonstrating the structures of the corresponding precursor adducts. This is made possible because of the easier interpretation of F-19 n.m.r.…”

Recent Advances in Microfluidic Synthesis

“…由于传热效率高, 高温或低温反应其温度可分别降 低或升高 [16,17] ; 反应时间也可大大缩短 [18] . 对于急剧放 热反应, 反应热可以很快散去, 消除了热斑; 减少了副 反应, 且提高了产物的选择性、产率和纯度 [14] .…”