“…Choosing of suitable composite systems permits creation of new phases in situ during sintering. Sintering additives in form of some elements (such as Al, Hf, Ti, B, C), and compounds (such as Al2O3, HfO2, TiO2, ZrO2, Si3N4, TiC, W2B5) are used at fabrication of in situ sintered B4C based ceramic composite materials [4,14,15]. They improve densification and influence the microstructure and mechanical properties of sintered compact because of creation of new secondary phases.…”