Four New Sb‐based Orthophosphates: Cation Regulation to Investigate Diversified Structural Architecture

Abstract

In the work, four new Sb-based phosphates, K 4 (SbO 2 ) 5 (PO 4 ) 3 , Rb(SbO 2 ) 2 PO 4 , Rb 3 (SbO 2 ) 3 (PO 4 ) 2 and Cs 3 (SbO 2 ) 3 (PO 4 ) 2 (H 2 O) 1.32 , were successfully synthesized by a high-temperature melt method. Among them, Rb(SbO 2 ) 2 PO 4 and Rb 3 (SbO 2 ) 3 (PO 4 ) 2 are the first reported examples of Rbcontaining alkali metal Sb-based phosphates. They show three-dimensional (3D) frameworks composed of [Sb 8 P 4 O 30 ] ∞ layer for K 4 (SbO 2 ) 5 (PO 4 ) 3 and [Sb 6 P 2 O 20 ] ∞ layer for Rb-(SbO 2 ) 2 PO 4 , and 2D lamellar structure composed of [Sb 3 P 2 O 10 ] ∞ for Rb 3 ( SbO 2 ) 3 (PO 4 ) 2 and Cs 3 (SbO 2 ) 3 (PO 4 ) 2 (H 2 O) 1.32 . A detailed structural comparison shows that the structure dimensions for them transfer from 1D to complex 3D framework with the increase of (Sb + P)/O ratio, which affects performances of the compounds. Optical property and energy band structure calculations were also carried out based on the density functional theory (DFT). The present study enriches the diversity of Sb-based phosphates and paves the way for further explore their optical properties in the future.

MB3P2S10 (M = Rb, Cs): two new alkali metal thioboratephosphates with [B6P4S20] T3-supertetrahedra

“…46–52 Beyond B–Q units, the [PQ 4 ] units in chalcophosphates also show abundant connection modes like isolated [PQ 4 ], ethane-like and edge-sharing [P 2 Q 6 ], corner-sharing [P 2 Q 7 ], [P 2 Q 9 ], [P 3 Q 7 ], and cyclic [P 3 Q 9 ] clusters, and also [P 3 S 10 ], [P 5 Se 12 ], and [P 6 Se 12 ], similar to the cases in phosphates. 53–61…”