Foundations of Thermodynamics

Abstract

Abstract. On the basis of new, concise foundations, this paper establishes the four laws of thermodynamics, the Maxwell relations, and the stability requirements for response functions, in a form applicable to global (homogeneous), local (hydrodynamic) and microlocal (kinetic) equilibrium.The present, self-contained treatment needs very little formal machinery and stays very close to the formulas as they are applied by the practicing physicist, chemist, or engineer. From a few basic assumptions, the full structure of phenomenological thermodynamics and of classical and quantum statistical mechanics is recovered.Care has been taken to keep the foundations free of subjective aspects (which traditionally creep in through information or probability). One might describe the paper as a uniform treatment of the nondynamical part of classical and quantum statistical mechanics "without statistics" (i.e., suitable for the definite descriptions of single objects) and "without mechanics" (i.e., independent of microscopic assumptions). When enriched by the traditional examples and applications, this paper may serve as the basis for a course on thermal physics.