Formation and hydrogenation of ethylidene on the Pt(111) surface

Deng, Rongping; Herceg, Eldad; Trenary, Michael

doi:10.1016/j.susc.2004.05.012

Cited by 45 publications

(63 citation statements)

References 49 publications

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“…Platinum single crystals of different orientation crystal faces have been used for H 2 /D 2 exchange [1][2][3], CO oxidation [4,5], and hydrocarbon conversion reactions like ethylene hydrogenation [6][7][8][9][10][11][12][13][14][15][16]. They revealed the surface structure sensitivity or insensitivity of different catalytic reactions, the roles of surface defects such as steps and kinks, and additives that are bonding or structure modifiers.…”

Section: Introductionmentioning

confidence: 99%

Fabrication of platinum nanoparticles and nanowires by electron beam lithography (EBL) and nanoimprint lithography (NIL): comparison of ethylene hydrogenation kinetics

et al. 2005

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Electron beam lithography (EBL), size reduction lithography (SRL), and nanoimprint lithography (NIL) have been utilized to produce platinum nanoparticles and nanowires in the 20-60-nm size range on oxide films (SiO 2 and Al 2 O 3 ) deposited onto silicon wafers. A combination of characterization techniques (SEM, AFM, XPS, AES) has been used to determine size, spatial arrangement and cleanliness of these fabricated catalysts. Ethylene hydrogenation reaction studies have been carried out over these fabricated catalysts and have revealed major differences in turnover rates and activation energies of the different nanostructures when clean and when poisoned with carbon monoxide. The oxide-metal interfaces are implicated as important reaction sites that remain active when the metal sites are poisoned by adsorbed carbon monoxide.

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Section: Introductionmentioning

confidence: 99%

Fabrication of platinum nanoparticles and nanowires by electron beam lithography (EBL) and nanoimprint lithography (NIL): comparison of ethylene hydrogenation kinetics

et al. 2005

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“…However, there is, to our knowledge, no report of the isolation and spectroscopic analysis of terminal alkylidenes on pure metal surfaces, although there are many examples of bridge-bonded surface alkylidenes [1][2][3][4]. This is consistent with the fact that metal surfaces present an array of contiguous atoms and, as in multinuclear organometallic complexes, l-alkylidene bonding is energetically preferred [5,6].…”

Section: Introductionmentioning

confidence: 86%

Preparation and olefin-metathesis activity of cyclopentylidene-oxo initiator sites on a molybdenum carbide surface

Siaj

Temprano

Dubuc

et al. 2006

Journal of Organometallic Chemistry

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“…However, several studies suggest that ethylidyne is actually an intermediate in a slow reaction path to ethane. Interestingly, the surface concentration of ethylidyne appears to have a maximum around room temperature [107].…”

Section: Ethylene Hydrogenationmentioning

confidence: 99%