Fluorine-free prepared two-dimensional molybdenum boride (MBene) as a promising anode for lithium-ion batteries with superior electrochemical performance

Xiong, Wei; Feng, Xingyu; Xiao, Yi; Huang, Tao; Li, Xiaoyan; Huang, Zhencheng; Ye, Shenghua; Li, Yongliang; Ren, Xiangzhong; Wang, Xinzhong; Ouyang, Xiaoping; Zhang, Qianling; Liu, Jianhong

doi:10.1016/j.cej.2022.137466

Cited by 58 publications

(52 citation statements)

References 46 publications

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“…In addition, due to the serious corrosiveness and toxicity of hydrofluoric acid, it is not recommended to use the same hydrofluoric acid etching strategy typically commonly used to manufacture MXene, so the preparation by Zhou et al [ 83 ] has not been applied to large-scale experiments. Xiong et al [ 85 ] recently reported a green and safe method to fabricate MBene from precursor, so as to promote the application research of MAB. They used a hydrothermal-assisted alkane solution etching method to prepare MoB from MoAlB (Fig.…”

Section: Synthesis Of Mbenesmentioning

confidence: 99%

“…When aluminum atoms are removed, 2D MoB can be observed from the etched region, but some regions are still not etched, and the end region of the wafer presents an etched style. Xiong et al [ 85 ] successfully prepared two-dimensional MoB wafers by hydrothermal assisted alkane solution etching, which opened the door for the future study of MBenes. Moreover, the samples obtained by using fluorine-free etchants have high safety, which is beneficial to the application in experiments.…”

Section: Synthesis Of Mbenesmentioning

confidence: 99%

“…The above is just a theoretical calculation to predict the excellent performance of different MBenes in the field of ion batteries. More recently, Xiong's team [ 85 ] prepare MoB by fluorine-free hydrothermal method, and test the electrochemical performance of MoB as a lithium ion battery in CR-2032 coin half battery. Figure 22 a shows the cyclic voltammetry (CV) curve of MoB in the voltage window of 0.01–3 V and Li/Li + .…”

Section: Potential Impact Of Mbenes In Energy Storagementioning

confidence: 99%

“…In addition, the results of theoretical calculations further confirm the excellent conductivity and high mechanical strength of MBenes. Very recently, Xiong's team [ 85 ] prepare MoB by fluorine-free hydrothermal method, and study electrochemical performance of MoB in LIBs.…”

Section: Summary and Perspectivesmentioning

confidence: 99%

“…2 i) as a promising anode material for sodium ion batteries. Very recently, Xiong and his group [ 85 ] prepared two-dimensional MoB with MoAlB as raw material by fluorine-free hydrothermal assisted alkane solution etching (Fig. 2 j), and further evaluated the electrochemical performance as anode materials for LIBs.…”

Section: Introductionmentioning

confidence: 99%

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A Rising 2D Star: Novel MBenes with Excellent Performance in Energy Conversion and Storage

Wang

Xiong

et al. 2022

Nano-Micro Lett.

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As a flourishing member of the two-dimensional (2D) nanomaterial family, MXenes have shown great potential in various research areas. In recent years, the continued growth of interest in MXene derivatives, 2D transition metal borides (MBenes), has contributed to the emergence of this 2D material as a latecomer. Due to the excellent electrical conductivity, mechanical properties and electrical properties, thus MBenes attract more researchers' interest. Extensive experimental and theoretical studies have shown that they have exciting energy conversion and electrochemical storage potential. However, a comprehensive and systematic review of MBenes applications has not been available so far. For this reason, we present a comprehensive summary of recent advances in MBenes research. We started by summarizing the latest fabrication routes and excellent properties of MBenes. The focus will then turn to their exciting potential for energy storage and conversion. Finally, a brief summary of the challenges and opportunities for MBenes in future practical applications is presented.

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Section: Synthesis Of Mbenesmentioning

confidence: 99%

Section: Synthesis Of Mbenesmentioning

confidence: 99%

Section: Potential Impact Of Mbenes In Energy Storagementioning

confidence: 99%

Section: Summary and Perspectivesmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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A Rising 2D Star: Novel MBenes with Excellent Performance in Energy Conversion and Storage

Wang

Xiong

et al. 2022

Nano-Micro Lett.

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Recent Advances in Non‐Ti MXenes: Synthesis, Properties, and Novel Applications

Khan,

Tareen,

Ahmad

et al. 2024

Advanced Science

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One of the most fascinating 2D nanomaterials (NMs) ever found is various members of MXene family. Among them, the titanium‐based MXenes, with more than 70% of publication‐related investigations, are comparatively well studied, producing fundamental foundation for the 2D MXene family members with flexible properties, familiar with a variety of advanced novel technological applications. Nonetheless, there are still more candidates among transitional metals (TMs) that can function as MXene NMs in ways that go well beyond those that are now recognized. Systematized details of the preparations, characteristics, limitations, significant discoveries, and uses of the novel M‐based MXenes (M‐MXenes), where M stands for non‐Ti TMs (M = Sc, V, Cr, Y, Zr, Nb, Mo, Hf, Ta, W, and Lu), are given. The exceptional qualities of the 2D non‐Ti MXene outperform standard Ti‐MXene in several applications. There is many advancement in top‐down as well as bottom‐up production of MXenes family members, which allows for exact control of the M‐characteristics MXene NMs to contain cutting‐edge applications. This study offers a systematic evaluation of existing research, covering everything in producing complex M‐MXenes from primary limitations to the characterization and selection of their applications in accordance with their novel features. The development of double metal combinations, extension of additional metal candidates beyond group‐(III–VI)B family, and subsequent development of the 2D TM carbide/TMs nitride/TM carbonitrides to 2D metal boride family are also included in this overview. The possibilities and further recommendations for the way of non‐Ti MXene NMs are in the synthesis of NMs will discuss in detail in this critical evaluation.

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Recent Developments and Future Perspectives of Molybdenum Borides and MBenes

Rout,

Shinde,

Patra

et al. 2024

Advanced Science

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Metal borides have received a lot of attention recently as a potentially useful material for a wide range of applications. In particular, molybdenum‐based borides and MBenes are of great significance, due to their remarkable properties like good electronic conductivity, considerable stability, high surface area, and environmental harmlessness. Therefore, in this article, the progress made in molybdenum‐based borides and MBenes in recent years is reviewed. The first step in understanding these materials is to begin with an overview of their structural and electronic properties. Then synthetic technologies for the production of molybdenum borides, such as high‐temperature/pressure methods, physical vapor deposition (PVD), chemical vapor deposition (CVD), element reaction route, molten salt‐assisted, and selective etching methods are surveyed. Then, the critical performance of these materials in numerous applications like energy storage, catalysis, biosensors, biomedical devices, surface‐enhanced Raman spectroscopy (SERS), and tribology and lubrication are summarized. The review concludes with an analysis of the current progress of these materials and provides perspectives for future research. Overall, this review will offer an insightful reference for the understanding molybdenum‐based borides and their development in the future.

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Fluorine-free prepared two-dimensional molybdenum boride (MBene) as a promising anode for lithium-ion batteries with superior electrochemical performance

Cited by 58 publications

References 46 publications

A Rising 2D Star: Novel MBenes with Excellent Performance in Energy Conversion and Storage

A Rising 2D Star: Novel MBenes with Excellent Performance in Energy Conversion and Storage

Recent Advances in Non‐Ti MXenes: Synthesis, Properties, and Novel Applications

Recent Developments and Future Perspectives of Molybdenum Borides and MBenes

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