“…In the field of fluorescence, PCW-substrates have been applied to observe coupled emissions in multiple directions as an extension of the SPCE methodology. , Though the earlier studies were not explicitly focused on taking advantage of the dual polarization, increased sharpness, and variable penetration depths of the WG modes, in more recent studies, these outstanding features have been employed for various applications. WG-coupling has been used to resolve multiple emission lines of Eu(III) ions, enhance fluorescence signals, monitor in situ growth of metal–organic frameworks, and selectively image emission from either the PCW surface or from the bulk solution. , However, so far, none of the studies have examined the role of emission dipole orientations on fluorescence coupling with the coexisting orthogonally polarized optical modes in PCW-substrates. The excitation and emission dipole orientations of a molecule are significant for determining its photophysics and interactions with the environment .…”