The application of geopolymer adhesive to CFRP-strengthened the RC structure is a new green reinforcement method, and the bonding behavior of geopolymer adhesive was studied in this paper. The geopolymer mechanical properties orthogonal test was conducted and the optimal proportion was obtained, which summarized the influence of slag powder content, liquid-solid ratio, and water glass modulus. A total of 15 adhesively bonded CFRP-concrete double-lap joints were fabricated and tested under shear loading to investigate the effect of geopolymer adhesive on the bonding behaviors. Modified bondslip models of the geopolymer adhesive specimens were developed and compared with the test date. The results showed that the failure models of epoxy adhesive and geopolymer adhesive are different. The bond strength, interface stiffness, and maximum shear stress of the geopolymer adhesive specimen can reach 93.6% ~97.6%, 95.7% ~132.9%, and 91% ~94% of the bond strength of epoxy adhesive respectively. The predicted τ max and s 0 of the proposed model are in excellent agreement with the experimental data, and the maximum deviation is À9.58%. This study proposes that geopolymer could be applied as an effective adhesive in the strengthening of RC structures.