Abstract:This contribution deals with flexographic printing of nanoparticulate tin-doped indium oxide (ITO) inks for the manufacture of fine lines on PET foils and glass substrates. The development and optimization of ITO inks, based on solutions of water and ethanol, for the flexographic printing process is presented. The influence of the solvent composition, of the particle content, and of the molar mass of the binder polyvinylpyrrolidone on the printing result is shown. ITO lines with a minimum line width of around … Show more
“…Enormous quantities of food packages and packaging foils receive their full-color branding and design by this technique every day, frequently using cost efficient and sustainable water-based inks. Not only the low-cost applications, but also highly specific energy and communication technologies define benchmarks for the development of flexography: printing conductive current-collecting grids on brittle silicon solar cells, or on transparent front electrodes for displays (see, e.g., [1]).…”
We considered pattern formation, i.e. viscous fingering, in the ink splitting process between an elastic flexographic printing plate and the substrate. We observed an unexpected scaling behavior of the emerging pattern length scale (i.e., finger width) as a function of printing velocity, fluid viscosity, surface tension, and plate elasticity coefficients. Scaling exponents depended on the ratio of the capillary number of the fluid flow, and the elastocapillary number defined by plate elasticity and surface tension. The exponents significantly differed from rigid printing plates, which depend on the capillary number only. A dynamic model is proposed to predict the scaling exponents. The results indicate that flexo printing corresponded to a self-regulating dynamical equilibrium of viscous, capillary, and elastic forces. We argue that these forces stabilize the process conditions in a flexo printing unit over a wide range of printing velocities, ink viscosities, and mechanical process settings.
“…Enormous quantities of food packages and packaging foils receive their full-color branding and design by this technique every day, frequently using cost efficient and sustainable water-based inks. Not only the low-cost applications, but also highly specific energy and communication technologies define benchmarks for the development of flexography: printing conductive current-collecting grids on brittle silicon solar cells, or on transparent front electrodes for displays (see, e.g., [1]).…”
We considered pattern formation, i.e. viscous fingering, in the ink splitting process between an elastic flexographic printing plate and the substrate. We observed an unexpected scaling behavior of the emerging pattern length scale (i.e., finger width) as a function of printing velocity, fluid viscosity, surface tension, and plate elasticity coefficients. Scaling exponents depended on the ratio of the capillary number of the fluid flow, and the elastocapillary number defined by plate elasticity and surface tension. The exponents significantly differed from rigid printing plates, which depend on the capillary number only. A dynamic model is proposed to predict the scaling exponents. The results indicate that flexo printing corresponded to a self-regulating dynamical equilibrium of viscous, capillary, and elastic forces. We argue that these forces stabilize the process conditions in a flexo printing unit over a wide range of printing velocities, ink viscosities, and mechanical process settings.
“…In contrast, the electrolytic interfaces used in an organic electrochemical transistor (OECT) [4][5][6][7][8][9][10][11][12][13][14] enable operation at very low voltages, typically less than 1 V, independent of the electrolyte thickness. This is of critical importance since it allows for device manufacturing via various printing techniques [15][16][17][18][19][20][21], despite the deposition of thicker layers at lower resolution and less smoothness. Due to the simple device architecture and low-voltage operation [22,23], the OECT is a versatile device platform that can be used in a wide variety of applications and research fields [3,[24][25][26][27].…”
The dimensions of the material serving as the channel in organic electrochemical transistors (OECTs) are important for the overall switching performance. Here, a laser ablation step is included in the OECT manufacturing process, in an attempt to shorten the channel length of the OECT. The source and drain electrodes are formed by laser ablation of a previously screen printed carbon-based rectangle, which in this study resulted in an average channel length equal to 25 µm. All other processing steps rely on screen printing, allowing for large-area manufacturing of OECTs and OECT-based circuits on flexible substrates. This approach results in a manufacturing yield of 89 %; 178 out of a total of 200 OECTs exhibited an ON/OFF ratio exceeding 1000 with a statistical mean value of 28,000 and reproducible switching performance. OECT-based circuits, here demonstrated by a logic inverter, provide a reasonably high voltage gain of 12. The results thus demonstrate another reliable OECT manufacturing process, based on the combination of laser ablation and screen printing.
“…The third area of printed applications relevant for electronics refers to conductive structures as, e.g., current‐conducting bars, nontransparent electrode structures or contact pads for, say, electroluminescent panels, printed batteries, solar cell back, and, sometimes, transparent front electrodes. [ 14 ] Typically, these structures are printed using concentrated preparations of nano‐ or micrometer‐sized metal and metal oxide particles, with a rheology close to gelation. This type of printing is readily established in electronics manufacturing, and the very domain of flexography and screen printing.…”
Section: Introductionmentioning
confidence: 99%
“…This is partly due to the complexity of the physics and chemistry behind the materials used there, the role of hydrophilic and hydrophobic interfaces. We should like to emphasize that there are considerable examples for a successful implementation of offset lithography [15,16] and flexography [7,14] in printed electronics. In this paper, we shall skip these topics, as many findings of principal importance can also be demon strated with conceptually minimalist printing techniques such as gravure and, in essence, inkjet.…”
Printing process development for fabrication of organic electronic devices is described, with focus on semiconductor layers for organic light‐emitting diodes and photovoltaic cells. This development is considerably more complex than for a graphical printing process. Key aspects are an adequate dosing and transfer of highly volatile inks, the reliable coalescence of the droplets deposited on the substrate to a closed liquid film, and the successful relaxation and leveling of the liquid–air interface in the solvent evaporation phase in the presence of Marangoni stresses and pattern formation instabilities. The conditions for successful implementation of a gravure or inkjet process, using steadily developing, new generations of polymer as well as small molecule semiconductors are, to a large extent, but not exclusively, originating from the molecular features of organic semiconductors and their printable solutions. In addition, recent developments in surface technology, and in the physics of thin‐film dynamics and spontaneous pattern formation contribute to a proper understanding of liquid layer dynamics in printed electronics. The role of ink formulation, Marangoni stresses related to concentration and temperature gradients, the effect of the disjoining pressure, and solvent evaporation are discussed.
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