“…This process is called new particle formation (NPF), where clusters are formed from the gaseous phase as a first step and, later on, grow to larger sizes (>100 nm) at which they can act as CCN (Hobbs et al, ; Mather et al, ) or ice nuclei (Hoyle et al, ) and impact the climate (Kerminen et al, ; Kulmala et al, , , ; Kulmala & Kerminen, ; Kulmala & Laaksonen, ; Makkonen et al, ). During active eruptions, both primary and secondary particles are present in different atmospheric vertical layers (Ilyinskaya et al, ; Mather & Pyle, ; Tulet et al, ). Conversely, during passive emissions, primary aerosols, with low concentrations, are often limited to the remobilization of accidental lithic (derived from the conduit and crater walls), while emissions of gaseous species may remain significant, likely to contribute to the formation of new particles.…”