First-principles materials study for spintronics: MnAs and MnN

Abstract

We report ab-initio all electrons density-functional calculations for the electronic structure of the compounds MnAs and MnN, in the zinc-blende phase. They are potential materials for use in fabrication of new functional semiconductors taking advantage of the spin degree of freedom. The aim is the establishing of the semiconductor spin electronics (spintronics) as a practical technology [H. Ohno, Semiconductor Science and Technology 17, 4 (2002).]. We compare results obtained using the theoretical approaches LDA (Local Density Approximation) and GGA (Generalized Gradient Approximation). The calculations are spin-polarized and we follow the evolution of the band structures as a function of lattice parameter. We compare also the evolution of the density of states of the majority-spins and of the minority-spins. We conclude that, depending on the lattice parameter, both materials may be half-metallic, therefore showing conduction by charge carriers of one spin direction exclusively: the majority-spin band is continuous, while the minority-spin has a gap. Both materials reach a total magnetization of the order of 4 µ B . MnN changes from paramagnetic to ferromagnetic with the increase of the lattice parameter.

First-principles study of structural, electronic and magnetic properties of AeX (Ae=Be, Mg, Sr, Ba; X=Si, Ge and Sn) compounds

“…Therefore, SrSi is a half-metallic ferromagnet. This result is similar to ZB-type CaC, CaSi and CaGe [17,18] and it is in contrast to similar half-metals like MnAs and CrAs, where the majority spins are metallic and a gap appears for the minority spins [28]. Here, the lowest lying band arises from the anion s-like states and not shown in figure. The upper valence band arises mainly from the anion p-like states.…”

Ab initiostudy of the magnetostructural properties of MnAs

“…More recently tight-binding 37,38 and first-principles [39][40][41][42][43][44][45][46][47] calculations have been performed for MnAs in the B8 1 structure showing a general good agreement with experiments. We are aware of only two studies dealing with the B31 structure.…”