First 12-tungstovanadate Keggin compound: synthesis and crystal structure of [Me4N]7[VW12O40]·15H2O

A novel polyoxometalate cluster decorated with the directly coordinated organonitrogen ligands: [As(phen)]2[As2Mo2O14]

“…In these fields, polyoxometalates (POMs), as one kind of significant metal oxide clusters, are outstanding inorganic building blocks for the construction of hybrid materials [4][5][6]. Meanwhile, mighty endeavors have been devoted to synthesize functionalized POM-based materials via incorporation or coordination of metal-organic units or organic moieties [7][8][9], and a large number of novel inorganic-metal organic hybrids combining transition metal complexes (TMCs) and POMs have been reported recently [10][11][12].…”

A novel polyoxometalate-based metal-organic compound constructed from an unprecedented [Ag8(Hpyttz)4(H2pyttz)2] cluster and an in-situ [VW12O40]3− anion

“…V-centered Keggin-type VW 12 polyoxoanion has been synthesized through several different methods and materials, which can coordinate with various metal-organic subunits forming different structures, as shown in Table S3 [21][22][23][24][25][26][27]. In this work, by introducing NH 4 [22], in which the saturated Keggin-type polyoxoanions are covalently linked by bimetallic compound [VO 2 Ag(phen) 3 ] 2+ .…”

Hydrothermal synthesis and characterization of (N(C2H5)4)4[VMo12V2O44]

“…Heteropolyoxometalates (HPOMs) have attracted an extensive interest in the contemporary material chemistry owing to the wide range of different structural characteristics and potential catalytic, photochemical, electrochromical and magnetic applications in recent years [1][2][3][4][5]. Therefore, synthesis and characterization of novel HPOMs with different topological properties are vital in order to discover their applications.…”