A novel polyoxometalate cluster decorated with the directly coordinated organonitrogen ligands: [As(phen)]2[As2Mo2O14]

Zhang, Yunan; Zhou, Baibin; Su, Zhanhua; Zhao, Zhifeng; Li, Chunxiang

doi:10.1016/j.inoche.2008.11.005

Cited by 7 publications

(1 citation statement)

References 26 publications

(27 reference statements)

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“…[33]. The above conclusion can be also supported by previous reports [20][21][22][23][24][25][26][27][33][34][35][36][37][38][39], which are listed in table 2, and the representative complexes are shown in figure 1. 1,10-Phenanthroline serves as an inhibitor, preventing As III from being oxidized to some extent [24]. To investigate the effect of pH on final products, a series of parallel experiments have been carried out; 1 was obtained in the pH range of 5.0-6.5, the most optimal pH was 6.0.…”

Section: Synthesissupporting

confidence: 85%

Designing a new organic-inorganic arsenomolybdate by modification of traditional Keggin-type building fragment

Hua

et al. 2013

Journal of Coordination Chemistry

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Niu (2013) Designing a new organic-inorganic arsenomolybdate by modification of traditional Keggin-type building fragment, Journal of Coordination Chemistry, 66:4, 725-736, A rare monocapped trivacant Keggin fragment [A-α-As III As V Mo 9 O 34 ] 6-has been captured and an organic-inorganic hybrid arsenomolybdate (AM) (H 2 en)[Ni(en) 2 (H 2 O)]{[Ni(en) 2 ][As III As VMo 9 O 34 ]}•3H 2 O (1) was obtained under hydrothermal conditions. The structure of 1 was determined by X-ray single-crystal diffraction and further characterized by IR spectroscopy, X-ray powder diffraction, scanning electron microscope with energy dispersive X-ray, and X-ray photoelectron spectroscopy. Single-crystal structural analysis indicates that 1 contains the peculiar monocapped trivacant [A-α-As III As V Mo 9 O 34 ] 6-fragment derived from the rare trivacant Keggin-type [A-α-As VMo 9 O 34 ] 9-unit capped by a triangular pyramidal {AsO 3 } group. Compound 1 represents the first Ni-substituted inorganic-organic AM containing the [A-α-As III As V Mo 9 O 34 ] 6-subunit.

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Section: Synthesissupporting

confidence: 85%

Designing a new organic-inorganic arsenomolybdate by modification of traditional Keggin-type building fragment

Hua

et al. 2013

Journal of Coordination Chemistry

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Self-assembly of γ-octamolybdate-based frameworks decorated by 1,3-bis(4-pyridyl)propane through covalent bond

Gu¹,

Jiang²,

Su³

et al. 2013

Inorganica Chimica Acta

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The synthesis, structure and properties of a new compound with 1D linear chain arsenomolybdate anion building block

Zhao

et al. 2015

Inorganic Chemistry Communications

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A novel polyoxometalate cluster decorated with the directly coordinated organonitrogen ligands: [As(phen)]2[As2Mo2O14]

Cited by 7 publications

References 26 publications

Designing a new organic-inorganic arsenomolybdate by modification of traditional Keggin-type building fragment

Designing a new organic-inorganic arsenomolybdate by modification of traditional Keggin-type building fragment

Self-assembly of γ-octamolybdate-based frameworks decorated by 1,3-bis(4-pyridyl)propane through covalent bond

The synthesis, structure and properties of a new compound with 1D linear chain arsenomolybdate anion building block

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