This paper presents the first comprehensive study of a groundbreaking Vertically Mounted Bifacial Photovoltaic (VBPV) system, marking a significant innovation in solar energy technology. The VBPV system, characterized by its vertical orientation and the use of high-efficiency Heterojunction (HJT) cells, introduces a novel concept diverging from traditional solar panel installations. Our empirical research, conducted over a full year at the University of York, UK, offers an inaugural assessment of this pioneering technology. The study reveals that the VBPV system significantly outperforms both a vertically mounted monofacial PV (VMPV) system and a conventional tilted monofacial PV (TMPV) system in energy output. Key findings include a daily power output increase of 7.12% and 10.12% over the VMPV system and an impressive 26.91% and 22.88% enhancement over the TMPV system during early morning and late afternoon hours, respectively. Seasonal analysis shows average power gains of 11.42% in spring, 8.13% in summer, 10.94% in autumn, and 12.45% in winter compared to the VMPV system. Against the TMPV system, these gains are even more substantial, peaking at 24.52% in winter. These results underscore the VBPV system's exceptional efficiency in harnessing solar energy across varied environmental conditions, establishing it as a promising and sustainable solution in solar energy technology.