Fered-Fenton process for the degradation of 1,4-dioxane with an activated carbon electrode: A kinetic model including active radicals

Removal of Bromocresol Green from aqueous solution by electro-Fenton and electro-Fenton-like processes with different catalysts: laboratory and kinetic model investigation

“…Electro-Fenton process is a complex system of many reactions, therefore the most suitable way to investigate kinetics of this process is kinetic model. Such an approach has been found to be very useful and many times lead to results being in good agreement with experimental data (Liu et al (2007), Mousset et al (2016), Nakagawa et al (2016)). Many presented so far kinetic models of the electro-Fenton process include specific pathways and intermediate compounds, thus they are limited to types of pollutants for which they were constructed.…”

The principle of detailed balancing, the iron-catalyzed disproportionation of hydrogen peroxide, and the Fenton reaction

“…These illegal loops have appeared in at least 122 publications. 5,7,8,11,14,17,[20][21][22][23]26,28,[30][31][32][33][35][36][37][38]55,60,66,67,69,70,[72][73][74]76,77,[81][82][83][84][85][86][87][89][90][91]93,[95][96][97]99,[112][113][114]124,[131][132]…”

“…If we disregard this concern, the consequences of this illegal loop in a mass-action mechanism can be explored by performing simulations of the loop based on the mechanism and parameters of a publication by Lin and Gurol 1998. 176 17,21,23,26,33,95,99,133,[176][177][178][179][182][183][184]187,189,190,193,195,197,198,200,203,204,206,207,211,218,219,[223][224][225]228 One of these shows the steps in the loop but then excludes them from the final model. 200 There are a few publications that use the inverse acid dependence in the first step of the loop (non-mass-action kinetics).…”

Recent Overview of Solar Photocatalysis and Solar Photo-Fenton Processes for Wastewater Treatment

“…These processes in situ generate the Fenton reagents (H 2 O 2 and/or Fe 2+ ) to yield OH • radicals [36,37]. The EF processes such as Fered-Fenton (EF-FeRe) [38,39], electrochemical peroxidation/anodic Fenton (EF-FeOx) [40][41][42], electro-Fenton (EF-H 2 O 2 -FeRe) [38,43], and peroxi-coagulation (EF-H 2 O 2 -FeOx) [44,45] increase the efficiency of pollutant degradation. The efficiency of pollutant degradation is enhanced when UV light or solar irradiation is used in combination with CF (photo-Fenton or solar photo-Fenton) and EF (photoelectro-Fenton or solar photoelectro-Fenton) processes.…”