The femtosecond laser-induced multi-photon polymerization of a zirconium–silicon based
sol–gel photopolymer was employed for the fabrication of a series of micro-optical
elements with single and combined optical functions: convex and Fresnel lenses,
gratings, solid immersion lenses on a glass slide and on the tip of an optical fiber.
The microlenses were produced as polymer caps of varying radii from 10 to 90
µm. The matching of refractive indices between the polymer and substrate was exploited for
the creation of composite glass-resist structures which functioned as single lenses.
Using this principle, solid immersion lenses were fabricated and their performance
demonstrated. The magnification of the composite solid immersion lenses
corresponded to the calculated values. The surface roughness of the lenses was below ∼ 30 nm, acceptable for optical applications in the visible range. In addition, the integration
of micro-optical elements onto the tip of an optical fiber was demonstrated. To
increase the efficiency of the 3D laser polymerization, the lenses were formed by
scanning only the outer shell and polymerizing the interior by exposure to UV light.