For a plasma with fixed total energy, number of particles, and momentum, the distribution function that maximizes entropy is a Boltzmann distribution. If, in addition, the rearrangement of charge is constrained, as happens on ion-ion collisional timescales for cross-field multiple-species transport, the maximum-entropy state is instead given by the classic impurity pinch relation. The maximum-entropy derivation, unlike previous approaches, does not rely on the details of the collision operator, only on the presence of certain conservation properties.