“…After filtration and solvent removal, the product was purified on silica gel using n-hexane and ethyl acetate to yield 4-formyl[2.2]paracyclophane as white crystals (10.4 g, 91.7%). 1 H NMR (400 MHz, DMSO-d 6 , δ): 9.94 (s, 1H, CHO), 7.03 (d, J = 2.0 Hz, 1H, Ar H), 6.81 (dd, J = 7.8, 2.0 Hz, 1H, Ar H), 6.65 (d, J = 7.8 Hz, 1H, Ar H), 6.58 (dd, J = 7.9, 1.9 Hz, 1H, Ar H), 6.51 (dd, J = 7.8, 1.9 Hz, 1H, Ar H), 6.41 (dd, J = 7.8, 1.9 Hz, 1H, Ar H), 6.26 (dd, J = 7.8, 1.9 Hz, 1H, Ar H), 4.06−3.95 (m, 1H; CH 2 ), 3.26−2.86 (m, 7H; CH 2 ). Next, 4-formyl[2.2]paracyclophane (7.4 g, 31.3 mmol) was dissolved in methyl alcohol (200 mL), and tetrahydrofuran (10 mL).…”