2022
DOI: 10.1016/j.electacta.2022.139935
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Facilitation of PdPb nanoalloy anchored on rGO/MOF-derived δ-Ga2O3 nanorod for electrocatalytic oxidation of methanol, ethanol and ethylene glycol

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Cited by 16 publications
(6 citation statements)
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“…28 The CO oxidation mass activity of Pd 1 Sn 0.40 /TiO 2 -GO (~1500 mA/mg Pd ) was 6.07 folds greater than Pt 1 Sn 0.40 /TiO 2 -GO and 8.82 folds than MOFs are new classes of materials, and their carbonized derivatives have unique physiochemical properties of carbon and catalytic merits of metals (i.e., great surface areas, multiple unsaturated coordination sites, well-crystalline structures, abundant active sites, and interior/exterior cavities), which can provide interconnected channels for reactants during CO oxidation. [30][31][32][33][34][35][36][37][38][39][40][41][42] Meanwhile, MOFs with plentiful unsaturated coordination sites and open inner/outer cavities can accommodate Pd nanocrystals, which results in higher stability aggregation and maximize Pd utilization during CO oxidation. 38,[43][44][45][46][47] There are few reports on using MOFs and their derivatives as supports for Pd nanocrystals for thermal CO oxidation.…”
Section: Introductionmentioning
confidence: 99%
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“…28 The CO oxidation mass activity of Pd 1 Sn 0.40 /TiO 2 -GO (~1500 mA/mg Pd ) was 6.07 folds greater than Pt 1 Sn 0.40 /TiO 2 -GO and 8.82 folds than MOFs are new classes of materials, and their carbonized derivatives have unique physiochemical properties of carbon and catalytic merits of metals (i.e., great surface areas, multiple unsaturated coordination sites, well-crystalline structures, abundant active sites, and interior/exterior cavities), which can provide interconnected channels for reactants during CO oxidation. [30][31][32][33][34][35][36][37][38][39][40][41][42] Meanwhile, MOFs with plentiful unsaturated coordination sites and open inner/outer cavities can accommodate Pd nanocrystals, which results in higher stability aggregation and maximize Pd utilization during CO oxidation. 38,[43][44][45][46][47] There are few reports on using MOFs and their derivatives as supports for Pd nanocrystals for thermal CO oxidation.…”
Section: Introductionmentioning
confidence: 99%
“…, high surface areas, multiple unsaturated coordination sites, well-crystalline structures, abundant active sites, and interior/exterior cavities), which can provide interconnected channels for reactants during CO oxidation. 30–42 Moreover, MOFs with numerous unsaturated coordination sites and open inner/outer cavities can accommodate Pd nanocrystals, which results in higher stability aggregation and maximize Pd utilization during CO oxidation. 38,43–47 There are a few reports on using MOFs and their derivatives as supports for Pd nanocrystals for thermal CO oxidation.…”
Section: Introductionmentioning
confidence: 99%
“…The increased scan rate leads to an increase of I f both under visible and dark conditions and a gradual shift of the peak potential towards a more positive direction owing to the irreversible charge transfer process of EG oxidation. 24 A good linear relationship exists between I f and the square root of the scan rate ( v 1/2 ) (Fig. 3e), which reflects that both the electrooxidation and photo-electrooxidation of EG are controlled by diffusion.…”
mentioning
confidence: 77%
“…[ 13 ] The above isomers and their various forms (including single crystals, nanomaterials, and thin films) are widely used in the field of Ga 2 O 3 ‐based SBPDs. [ 14–20 ]…”
Section: Introductionmentioning
confidence: 99%