Facile synthesis of shape and size tunable porphyrinoid coordination polymers: from copper porphyrin nanoplates to microspindles

Abstract

Size tunable copper porphyrin dispersed nanoplates, assembled nanoplates, and microspindles have been controllably fabricated by a simple surfactant-assisted solution route.

Facile synthesis and characterizations of copper–zinc-10,15,20-tetra(4-pyridyl) porphyrin (Cu–ZnTPyP) coordination polymer with hexagonal micro-lump and micro-prism morphologies

“…As shown in Fig.2, the Cu-ZnTPyP hexagonal micro-lumps and micro-prisms exhibit similar XRD patterns (curve a), which are different from the previously reported CuTPyP micro-spindles(curve d) [16]. By comparing with previous reports, we find that the XRD patterns for the two [19].…”

“…In recent years, the design and synthesis of well-defined ICPs with porphyrin building blocks has become a very attractive topic in scientific research. Huang and coworkers [16] have reported the synthesis of nano-plates and micro-spindles nanostructures by using copper-tetrapyridylporphyrin coordination polymers (CuTPyP). The suggested growth mechanism reveals that the formation of micro-spindles could be achieved from the interaction between the central coordination and peripheral pyridyl functional groups in porphyrin molecules.…”

Morphological study and potential applications of nano metal–organic coordination polymers

“…35B). 200 Thus, the formation of either nanoplates or micro-spindles is controlled by the existence of a surfactant. Utilizing this route and by controlling the reaction parameters, size-tunable micro-spindles ranging from 500 nm to 5 mm and nano-plates ranging from 500 nm to 1 mm have been obtained (Fig.…”

Lanthanides MOFs (Samarium, Europium, and Terbium) Characteristics and Its Possible Potentials

“…There are at least 11 methods to synthesize MOFs that have been developed by humans [6], such as solvo/hydrothermal synthesis [7], sonochemistry [8], slow diffusion [9], conventional heating [10], temperature-controlled cooling [11], gel growth crystallization technique [12], microwave synthesis [13], rapid precipitation procedure [14], electrochemical synthesis [6], modulation synthesis [15] and microfluidic synthesis [16]. Among the eleven…”