Facile synthesis of palladium nanoparticles encapsulated in amine-functionalized mesoporous metal–organic frameworks and catalytic for dehalogenation of aryl chlorides

TiO2 encapsulated in Salicylaldehyde-NH2-MIL-101(Cr) for enhanced visible light-driven photodegradation of MB

“…NH 2 -MIL-101(Cr) retains the features of MIL-101, in which amino groups are introduced into the organic frames of the MOF lattice [20]. NH 2 -MIL-101(Cr) can be a good candidate for PSM due to its large pores, good thermal stability as well as excellent chemical stability to water and common organic solvents [21]. Moreover, the reactive amino groups existing on the surface of the NH 2 -MIL-101(Cr) pores can provide versatility to covalently attach functional species.…”

Metal–organic framework MIL-53(Al)-supported copper catalyst for CO catalytic oxidation reaction

“…With high pore volume, large surface area and geometrical control, MOFs have more extensive applications than other porous materials, such as for adsorption separation, catalysts, optical and battery materials [6][7][8][9][10]. Catalysis based on MOFs includes cyanosilylation of benzaldehyde and acetone [11], oxidation of alkanes, olefins, alcohols, and amines [12][13][14][15][16][17], hydroxylation of aromatic compounds [18], hydrolysis of esters, esterification of acetic acid with 1-propanol [19], and regioselective ring opening of epoxides [20]. Most of these MOFs catalyzed reactions are in liquid phase [21].…”

Application of metal and metal oxide nanoparticles@MOFs

“…Such transformations include Suzuki-Myaura [94][95][96][97], Sonogashira [97,98], Ulmann [94], and Heck [99] reactions. Compared to other metal M a n u s c r i p t 15 A wide range of applications, including chemical threat detection, medical diagnostics, food/drink quality control, explosives and pollutants detection, requires sensors that detect specific molecules or elements with high selectivity, sensitivity, and speed of analysis [125][126][127].…”

“…An illustrative example was reported by Yuan et al, who developed a very efficient Pd@MIL-101(Cr) catalyst for water mediated Suzuki-Miyaura and Ullmann coupling reactions. This catalyst showed high stability, low metal leaching and high activities (conversion = 100 %) over a large number of cycles[94].List of MOF supported metal nanoparticle catalysts by reaction and substrate.…”