“…Cadmium sulfide, due to its suitable band gap position and light sensitizing ability, is considered as a promising photocatalyst material, its nanostructures have been investigated extensively in solar-driven PEC, photocatalysis and solar cell applications. − However, some critical shortcomings such as its limited visible-light absorption regime, low charge-transfer rate, and fast recombination limit its PEC energy conversion efficiency. ,, Among the noble metals, Ag is an inexpensive metal, and Ag NPs <30 nm under visible-light illumination exhibit strong surface plasmon resonance and produce highly energetic hot electrons through nonradiative decay, resulting in enhanced optical absorption, charge separation, and thus improved PEC performance . The production of highly energetic hot electrons and cost effectiveness make it a good alternative to expensive noble metals such as Au NPs and an ideal choice for large-scale applications.…”