2012
DOI: 10.1039/c2ce25205h
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Facile route fabrication of nano-Ni core mesoporous-silica shell particles with high catalytic activity towards 4-nitrophenol reduction

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Cited by 113 publications
(55 citation statements)
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“…This suggests that the heterogeneous reduction of 4-NPh in our case is a surface phenomenon. The obtained activation energy is much smaller than that reported by several other studies [44][45][46], which may be attributed to the larger surface area provided by the smaller size of synthesised Ni NPs.…”
Section: Kinetics and Thermodynamics Of 4-nph Reductioncontrasting
confidence: 81%
“…This suggests that the heterogeneous reduction of 4-NPh in our case is a surface phenomenon. The obtained activation energy is much smaller than that reported by several other studies [44][45][46], which may be attributed to the larger surface area provided by the smaller size of synthesised Ni NPs.…”
Section: Kinetics and Thermodynamics Of 4-nph Reductioncontrasting
confidence: 81%
“…The specific surface areas, pore sizes and pore volumes data of the as-prepared catalysts calculated by BET and BJH methods were summarized in Table 1. All the g-C 3 N 4 based photocatalysts are type IV with H3 hysteresis loops according to the IUPAC classification, indicating the presence of mesopores [71][72][73][74]. As shown in Table 1, the pure g-C 3 N 4 showed a BET surface area of ∼49.5 m 2 /g.…”
Section: N 2 Adsorption-desorption Studiesmentioning
confidence: 98%
“…Other metallic NPs such as Pt [108] Ni [143], Zn [144], Co [145] and Ru [146] NPs (or their alloy NPs) are also involved in the 4-NP reduction. Their apparent rate constant together with PdNPs, AgNPs and CuNPs are collected in Table 2.…”
Section: Other Metallic Nps Catalyzed 4-np Reaction and Their Comparimentioning
confidence: 99%