fac-Cobalt(III)-azido complexes derived from substituted pyridyl-based tridentate amines

Massoud, Salah S.; Spell, Mark L.; Haq, Zadid K.; Mautner, Franz-Andreas

doi:10.1007/s11243-014-9837-6

Cited by 7 publications

(1 citation statement)

References 58 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The ligand N-methyl(2-(2-pyridyl)ethyl)-(4-methoxy-3,5-dimethyl-2-pyridylmethyl)amine (dmMePEA) was prepared according to the published procedure. 40 Infrared spectra were recorded on a JASCO FT/IR-480 plus spectrometer as KBr pellets. Electronic spectra were recorded using an Agilent 8453 HP diode UV-Vis spectrophotometer.…”

Section: Materials and Physical Measurementsmentioning

confidence: 99%

Magneto-structural properties of carbonato-bridged copper(ii) complexes: fixation of atmospheric CO₂

et al. 2015

Self Cite

View full text Add to dashboard Cite

Two carbonato-bridged Cu(II) complexes, [Cu 3 (dmMePEA) 3 (m 3 -CO 3 )(ClO 4 ) 3 ]ClO 4 (1) and [Cu 2 (iptren) 2 (m 2 -CO 3 )]-(ClO 4 ) 2 ÁH 2 O (2), (dmMePEA = N-methyl(2-(2-pyridyl)ethyl)-(4-methoxy-3,5-dimethyl-2-pyridylmethyl)amine, iptren = tris[2-(isopropylamino)ethyl]amine) were synthesized through the atmospheric fixation of CO 2 . The complexes were structurally and magnetically characterized. Tris(bidentate) and bis (monodentate) carbonato-bridge bonding modes were found in the two complexes. Variable temperature magnetic susceptibility (2-300 K) revealed weak bulk ferromagnetic coupling in complex 1 (J = 1.1 cm À1 ) and very strong antiferromagnetic coupling in 2 (J = À167.7 cm À1 ). The magnetic properties of the two complexes are discussed as a function of their structure parameters and in relation to those of other related complexes of similar carbonato-bridging bonding modes.Chart 1 Coordination modes of m 3 -and m 2 -carbonato-bridged M(II) complexes. Chart 2The structural formulas of ligands used in this study together with related tri-and tripodal tetra-dentate amines.

show abstract

Section: Materials and Physical Measurementsmentioning

confidence: 99%

Magneto-structural properties of carbonato-bridged copper(ii) complexes: fixation of atmospheric CO₂

et al. 2015

Self Cite

View full text Add to dashboard Cite

show abstract

Azido- and chlorido-cobalt complex as carrier-prototypes for antitumoral prodrugs

Pires

Giacomin

Castro

et al. 2016

Journal of Inorganic Biochemistry

View full text Add to dashboard Cite

Syntheses and non-covalent interactions of naphthalene-bearing Schiff base complexes of Zn(II), Co(III), Cu(II) and V(IV): Selective detection of Zn(II)

et al. 2016

View full text Add to dashboard Cite

fac-Cobalt(III)-azido complexes derived from substituted pyridyl-based tridentate amines

Cited by 7 publications

References 58 publications

Magneto-structural properties of carbonato-bridged copper(ii) complexes: fixation of atmospheric CO₂

Magneto-structural properties of carbonato-bridged copper(ii) complexes: fixation of atmospheric CO₂

Azido- and chlorido-cobalt complex as carrier-prototypes for antitumoral prodrugs

Syntheses and non-covalent interactions of naphthalene-bearing Schiff base complexes of Zn(II), Co(III), Cu(II) and V(IV): Selective detection of Zn(II)

Contact Info

Product

Resources

About

fac-Cobalt(III)-azido complexes derived from substituted pyridyl-based tridentate amines

Cited by 7 publications

References 58 publications

Magneto-structural properties of carbonato-bridged copper(ii) complexes: fixation of atmospheric CO2

Magneto-structural properties of carbonato-bridged copper(ii) complexes: fixation of atmospheric CO2

Azido- and chlorido-cobalt complex as carrier-prototypes for antitumoral prodrugs

Syntheses and non-covalent interactions of naphthalene-bearing Schiff base complexes of Zn(II), Co(III), Cu(II) and V(IV): Selective detection of Zn(II)

Contact Info

Product

Resources

About

Magneto-structural properties of carbonato-bridged copper(ii) complexes: fixation of atmospheric CO₂

Magneto-structural properties of carbonato-bridged copper(ii) complexes: fixation of atmospheric CO₂