Abstract:Doping and forming solid solution is an effective approach to tailor densification and grain growth. In this study, submicron Li2(Ti,Zr)O3 solid solution ceramics was successfully fabricated by a modified solid‐state route for the first time. The use of appropriate starting powders can greatly reduce the synthesis temperature, and the preparation of Li2(Ti,Zr)O3 with submicron grain size is possible. The substitution of Ti by Zr will inhibit the phase transition from cubic to monoclinic structure, as well as t… Show more
“…These values were low compared with the Li 2 TiO 3 pebbles fabricated by the other methods and similar to those of Li 4 SiO 4 -Li 2 TiO 3 biphasic pebbles fabricated by melt process; the crush loads of Li 2 TiO 3 pebbles by emulsion method, 34 Li 2 TiO 3 pebbles by piezoelectric microdroplet jetting, 11 Li-rich Li 2 TiO 3 pebbles by rolling method, 35 and Li 4 SiO 4 -Li 2 TiO 3 pebbles by melt process 24 are 37.2, 25.7, 10-41, and 5-15 N. Crush load of the pebbles could be improved by an additional heat treatment and/or compositional modification, as reported in the previous studies. 22,36 Particularly, an addition of Li 2 CO 3 to the initial powder as a sintering aid may contribute both to densification and increase of Li/Ti ratio. 37 F I G U R E 4 Size distributions of the pebbles fabricated with the laser powers of 6.9 J (A), 7.9 J (B), 9.0 J (C), and 9.8 J (D).…”
A large amount of Li-containing ceramic breeder pebbles is packed in the solid breeding blanket of a nuclear fusion reactor. Several pebble fabrication technologies have been proposed in previous studies, including wet process, emulsion method, extrusion spheronization, additive manufacturing, and melt process.However, a simple, energy-effective, and scalable fabrication technology remains to be developed for the automated mass production and reprocessing of used radioactive pebbles post-operation. Selective laser melting potentially enables the quick and automated fabrication of breeder pebbles. Herein, we employ a high-power density pulse laser to produce ceramic breeder pebbles. A pulsed YAG laser was irradiated over a lithium metatitanate (Li 2 TiO 3 ) powder bed in air, and the corresponding temperature was monitored using fiber-type infrared pyrometers. Spherical Li 2 TiO 3 pebbles were successfully fabricated in a single step with an average diameter of 0.78 ± 0.13 μm and the sintering density of 87.4% ± 5.6% (input power: 7.9 J/pulse). The irradiated Li 2 TiO 3 powder melted and turned spherical under surface tension and rapidly solidified, resulting in uniaxial fine grains and a decrease in the degree of long-range cation ordering.
“…These values were low compared with the Li 2 TiO 3 pebbles fabricated by the other methods and similar to those of Li 4 SiO 4 -Li 2 TiO 3 biphasic pebbles fabricated by melt process; the crush loads of Li 2 TiO 3 pebbles by emulsion method, 34 Li 2 TiO 3 pebbles by piezoelectric microdroplet jetting, 11 Li-rich Li 2 TiO 3 pebbles by rolling method, 35 and Li 4 SiO 4 -Li 2 TiO 3 pebbles by melt process 24 are 37.2, 25.7, 10-41, and 5-15 N. Crush load of the pebbles could be improved by an additional heat treatment and/or compositional modification, as reported in the previous studies. 22,36 Particularly, an addition of Li 2 CO 3 to the initial powder as a sintering aid may contribute both to densification and increase of Li/Ti ratio. 37 F I G U R E 4 Size distributions of the pebbles fabricated with the laser powers of 6.9 J (A), 7.9 J (B), 9.0 J (C), and 9.8 J (D).…”
A large amount of Li-containing ceramic breeder pebbles is packed in the solid breeding blanket of a nuclear fusion reactor. Several pebble fabrication technologies have been proposed in previous studies, including wet process, emulsion method, extrusion spheronization, additive manufacturing, and melt process.However, a simple, energy-effective, and scalable fabrication technology remains to be developed for the automated mass production and reprocessing of used radioactive pebbles post-operation. Selective laser melting potentially enables the quick and automated fabrication of breeder pebbles. Herein, we employ a high-power density pulse laser to produce ceramic breeder pebbles. A pulsed YAG laser was irradiated over a lithium metatitanate (Li 2 TiO 3 ) powder bed in air, and the corresponding temperature was monitored using fiber-type infrared pyrometers. Spherical Li 2 TiO 3 pebbles were successfully fabricated in a single step with an average diameter of 0.78 ± 0.13 μm and the sintering density of 87.4% ± 5.6% (input power: 7.9 J/pulse). The irradiated Li 2 TiO 3 powder melted and turned spherical under surface tension and rapidly solidified, resulting in uniaxial fine grains and a decrease in the degree of long-range cation ordering.
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