We
proposed a new concept of increasing the plasticity of chalcogenide
glasses while maintaining a high glass transition temperature. The
main idea of this concept lies in the formation of Ag–Ag metallophilic
interactions when silver chalcogenide is introduced into the glass
composition. This suggestion was confirmed by the experimental study
of glasses based on the Ag2Se–Sb2Se3–GeSe2 system. It was observed that the
introduction of 40 mole percent of Ag2Se into the glass
composition leads to the increase of its plasticity by 3.5 times,
whereas the glass transition temperature of such glass remains higher
than 200 °C. The most typical application area of these materials
is infrared (IR) optics. In our case, the addition of silver not only
improves the mechanical properties of a glass but also allows one
to keep the position of the fundamental absorption edge in the near-IR
region (900 nm), which is quite suitable for the aforementioned applications.