“…Advent of electroceramic compounds like CaCu 3 Ti 4 O 12 (CCTO) [1,2] with giant dielectric constant is a big boost in this field as it can allow miniaturization of capacitive components, thereby shrinking the size of electronic devices. The stunning dielectric features of this toxic free compound has already been tested for applications like multi-layer ceramic capacitors (MLCC) [3], microwave devices and antennas [4], gas and humidity sensor [5,6], supercapacitor [7,8] etc. Despite the advantage of unusually high dielectric constant (ε r ∼ 10 4 -10 5 ) of CCTO, a member of ACu 3 Ti 4 O 12 family having body centred cubic perovskite structure, it is always associated with considerably high dielectric tangent loss (tan δ > 0.05 at 1 kHz at room temperature) together with low breakdown voltage, which cast a shadow on its application in capacitor.…”