“…Both CoO and Co 3 O 4 are known as direct transition p-type semiconductors [12,13], which are paramagnetic around room-temperature with band gaps of 2.2-2.8 eV and 1.4-1.8 eV [14,15], and Néel temperature T N of 291 K and 40 K, respectively. Recently, nanocrystalline CoO has been reported as a photocatalyst for water splitting by visible-light irradiation [16], and both CoO and Co 3 O 4 have potential applications in devices such as battery electrodes [17], gas sensors [15,[18][19][20], solar-selective absorbers [21] and spintronic devices through the formation of exchange bias layers [22]. Epitaxial thin films or layers of these cobalt oxides have been grown by several methods, including PLD [23][24][25], molecular beam epitaxy [26][27][28][29], atomic layer deposition [30][31][32], chemical vapor deposition [33], sol-gel [34], thermal evaporation [35], and surface oxidation of metallic cobalt [36,37].…”