Abstract:This tutorial review covers the history, current progress, and future research directions of interfacial polymerization for making high-performance desalination membranes.
Membranes used for desalination still face challenges during operation. One of these challenges is the buildup of salt ions at the membrane surface. This is known as concentration polarization, and it has a negative effect on membrane water permeance and salt rejection. In an attempt to decrease concentration polarization, a line-and-groove nanopattern was applied to a nanofiltration (NF) membrane. Aqueous sodium sulfate (Na2SO4) solutions were used to test the rejection and permeance of both pristine and patterned membranes. It was found that the nanopatterns did not reduce but increased the concentration polarization at the membrane surface. Based on these studies, different pattern shapes and sizes should be investigated to gain a fundamental understanding of the influence of pattern size and shape on concentration polarization.
Membranes used for desalination still face challenges during operation. One of these challenges is the buildup of salt ions at the membrane surface. This is known as concentration polarization, and it has a negative effect on membrane water permeance and salt rejection. In an attempt to decrease concentration polarization, a line-and-groove nanopattern was applied to a nanofiltration (NF) membrane. Aqueous sodium sulfate (Na2SO4) solutions were used to test the rejection and permeance of both pristine and patterned membranes. It was found that the nanopatterns did not reduce but increased the concentration polarization at the membrane surface. Based on these studies, different pattern shapes and sizes should be investigated to gain a fundamental understanding of the influence of pattern size and shape on concentration polarization.
“…Thin-film membranes with nanocomposite structures are used mainly in commercial water desalination. They can be prepared using combined phase conversion and interfacial polymerization technologies [8]. Conventional interfacial polymerization remains the most popular method to make thin-film RO and NF membranes.…”
Nowadays, acquiring a water supply for urban and industrial uses is one of the greatest challenges facing humanity for ensuring sustainability. Membrane technology has been considered cost-effective, encompasses lower energy requirements, and at the same time, offers acceptable performance. Electrospun nanofibrous membranes (ENMs) are considered a novel and promising strategy for the production of membranes that could be applied in several treatment processes, especially desalination and ion removal. In this study, we apply an unsupervised machine-learning strategy, the so-called principal component analysis (PCA), for the purpose of seeking discrepancies and similarities between different ENMs. The main purpose was to investigate the influence of membrane fabrication conditions, characteristics, and process conditions in order to seek the relevance of the application of different electrospun nanofibrous membranes (ENMs). Membranes were majorly classified into single polymers/layers, from one side, and dual multiple layer ENMs, from another side. For both classes, variables related to membrane fabrication conditions were not separated from membrane characterization variables. This reveals that membranes’ characteristics not only depend on the chemical composition, but also on the fabrication conditions. On the other hand, the process conditions of ENM fabrication showed an extensive effect on membranes’ performance.
“…Reaction between m -phenylenediamine (MPD) and trimesoyl chloride (TMC) occurs at the surface of a microporous polysulfone support to form a thin polyamide layer. Reproduced with permission from Lu and Elimelech (2021) , Copyright 2021, Royal Society of Chemistry. (B–D) Schematic illustration of formation of nanoparticle-induced crumpled polyamide nano-filtration membrane.…”
Section: Fabrication Strategies Of Membranesmentioning
confidence: 99%
“…Figure 4 D shows that introducing hydrophobic materials may improve their dispersibility in the polyamide matrix, thereby inhibiting the formation of the defect channels, and thus the high liquid entry pressure in these hydrophobic nanopores would provide additional resistance to water transport ( Yin et al., 2020 ). Although hydrophobic mesoporous material (∼4 nm) is another option to avoid defects, a required pressure of 138 bar is simply beyond the maximum operating pressure in typical RO systems (i.e., ∼80 bar) ( Lu and Elimelech, 2021 ). Despite the wide use of IP process to fabricate membranes for wastewater treatment, several technical obstacles have hampered the use of IP methods, which largely stem from the inherent limitations of the polyamide chemistry and reaction mechanisms.…”
Section: Fabrication Strategies Of Membranesmentioning
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