To date, polylactic acid (PLA) composites
with a uniform dispersion
of fillers have been extensively studied. However, there is little
research about the shape memory (SM) behavior of a PLA composite
in which the nanoclays have a nonuniform dispersion. In this paper,
the alkaline calcium bentonite (ACBT) was first modified by citric
acid (CA) to improve the compatibility between bentonite (BT) and
PLA. The structure of CA-modified bentonite (CABT) was characterized
by Fourier transform infrared spectroscopy (FT-IR), thermogravimetric
analysis (TGA), X-ray diffraction (XRD), and scanning electron microscopy
(SEM). Then the CABT/PLA composite with gradient concentration of
CABT in thickness direction was fabricated. Because of the good affinity
between the grafted CA and the ester groups, the CABT imposed powerful
restrictions on the PLA chains, which contributed to the anisotropic
driving force for shape recovery. The relationship between the structure
and the properties and the mechanism of anisotropic SM behavior of
composite were studied.