In this paper modes of action of passive fire protection agents, incorporated chemically into materials and products, are discussed in terms of resistance to igni tion and fire pr opagat ion and reduction in heat release r-a te. The effectiveness of these agents in large-scale fires, to enhance the ease of fire control, suppression and extinguishment by water, in warehouses is evaluated. All the experiments were performed in the Factory Mutual Research Corporation's 50 kW-, 500 kW-and 10,000 kW-Scale Flammability Apparatuses. a~heat of combustion (kJ/g) Kt~thermally thick response parameter (kW_s 1/ 2/m2) K t n thermally thin response parameter (kW-s/m 2) k thermal conductivity (kW/m-K) m exponent !?II exponent 9 heat flux (kW/m 2) Q heat release rate (kW) T temperature (K) FIRE SAFETY SCIENCE-PROCEEDINGS OF THE THIRD INTERNATIONAL SYMPOSIUM.