2008
DOI: 10.1063/1.3049130
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Explosive vapor sensor using poly (3-hexylthiophene) and CuII tetraphenylporphyrin composite based organic field effect transistors

Abstract: Organic field effect transistors based on poly(3-hexylthiophene) and CuII tetraphenylporphyrin composite were investigated as sensors for detection of vapors of nitrobased explosive compounds, viz., 1,3,5-trinitro-1,3,5-triazacyclohexane (RDX), 2,4,6-trinitrotoluene (TNT), and dinitrobenzene, which are also strong oxidizing agents. Significant changes, suitable for sensor response, were observed in transistor “on” current (Ion) and conductance (S) after exposure. A similar device response was, however, not obs… Show more

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Cited by 45 publications
(16 citation statements)
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“…Meanwhile, the complementary ring oscillator showed a higher voltage‐gain of ∼20 (enhanced detection of low analyte concentrations) and more adaptive feedback (improved background elimination) than the discrete transistor sensor. Fifthly, the employment of composite thin films as sensor active layers has been used to detect explosive vapors 156. In fact, composites are likely to exhibit enhanced sensitivity to other classes of chemical substances.…”
Section: Sensors Based On Organic Field‐effect Transistors (Sofets)mentioning
confidence: 99%
“…Meanwhile, the complementary ring oscillator showed a higher voltage‐gain of ∼20 (enhanced detection of low analyte concentrations) and more adaptive feedback (improved background elimination) than the discrete transistor sensor. Fifthly, the employment of composite thin films as sensor active layers has been used to detect explosive vapors 156. In fact, composites are likely to exhibit enhanced sensitivity to other classes of chemical substances.…”
Section: Sensors Based On Organic Field‐effect Transistors (Sofets)mentioning
confidence: 99%
“…A special case of a “receptor” moiety is Cu tetraphenylporphyrin (TPP) acting as a complexing agent for nitro compounds through donor‐acceptor interactions. The addition of Cu TPP to a P3HT film in an OFET made the device sensitive to a wider range of nitrated explosives, including 1,3,5‐trinitro‐1,3,5‐triazacyclohexane (RDX), than was the original P3HT film alone 17. A combined coordination to the Cu and electron extraction by the RDX was believed responsible.…”
Section: Organic Field‐effect Transistors As Chemical Sensorsmentioning
confidence: 99%
“…Many types of electrical transducer platforms utilizing organic semiconductors have been proposed and engineered to detect chemical compounds. The majority of chemical sensors are built on conventional platforms of resistors [1][2][3][4] and field-effect transistors [5][6][7][8][9]. The indication of chemical detection of these devices is mainly the change in resistance.…”
Section: Introductionmentioning
confidence: 99%