Exploration of New Biomass‐Derived Solvents: Application to Carboxylation Reactions

Abstract

Supporting Information and the ORCID identification number(s) for the author(s) of this article can be found under: https://doi.org/10.

Antidepressant activity of rose oxide essential oil: possible involvement of serotonergic transmission

“…RO can also be produced through the photo oxygenation of citronellol ( Alsters et al., 2010 ; Xiao et al., 2017 ). Due to its commercial application, many studies report the use of rose oxide in the production of aromas and reactions of drug production ( Cavazzana et al., 2018 ; Gevorgyan et al., 2020 ; Guo et al., 2020 ; Xiao et al., 2017 ). Besides having a delicate, sweet and mild aroma, the rose essential oil has been described as a compound that has anti-inflammatory, calming, relaxing and antioxidant effects ( Guo et al., 2020 ; Nonato et al., 2012 ).…”

The green solvent: a critical perspective

“…Bio-derived or potentially bio-derived 33 products have been investigated in the search for wholly new materials to replace solvents of concern. Biomass-derived, or potentially biomass-derived, solvents have also been used as media in which to carry out CO 2 -based carboxylations (Gevorgyan et al 2020 ). These included polar aprotic biomass-derived ethers [ 2-methyltetrahydrofuran , acetaldehyde diethyl acetal , isosorbide dimethyl ether , 2,2-dimethyl-1,3-dioxolane-4-methanol (Cyrene®), eucalyptol (also known as 1,8-cineol ), Rose oxide ] and esters (γ-valerolactone, diethyl succinate , ethyl acetate ), as well as non-polar aprotic unsaturated terpenes and their derivatives [ γ-terpinene , α-pinene , (R)-( + )limonene , p-cymene ].…”

“…Most of these have been assembled from various compilations and data sets used in the computerised identification and selection of solvents with particular characteristics and are discussed in “ Solvent selection and design: empirical database and computational methods ” section. Some materials cited as green in additional papers [and from one website ( http://www.xftechnologies.com/solvents )] are also included (Bankar et al 2013 ; Barbaro et al 2020 ; Bauer and Kruse 2019 ; Bergez-Lacoste et al 2014 ; Byrne et al 2017 ; Byrne et al 2018 ; Calvo‑Flores et al 2018 ; Christy et al 2018 ; Clark et al 2017a ; Cseri and Szekely 2019 ; Di Girolamo et al 2021 ; Diorazio et al 2016 ; Driver and Hunter 2020 ; Estévez 2009 ; Gevorgyan et al 2020 ; Ho et al 2020 ; Hu et al 2014 ; Jessop et al 2012 ; Jin et al 2017 ; Kobayashi et al 2019 ; Lee et al 2017 ; Linke et al 2020 ; Marcel et al 2019 ; Moity et al 2014a , b ; Mudraboyina et al 2016 ; Murray et al 2016 ; Pellis et al 2019 ; Piccione et al 2019 ; Qian et al 2021 ; Samorì et al 2014 ; Shahbazi et al 2020 ; Shakeel et al 2014 ; Sherwood et al 2016 ; Strohmann et al 2019 ; Tobiszewski et al 2015 ; Vinci et al 2007 ; Wypych and Wypych 2014 , 2019 ; Yang and Sen 2010 ; Yara-Varón et al 2016; Zhenova et al 2019 ).…”

From Simple Alkenes and CO2 to Fluorinated Carboxylic Acids: Computational Studies and Predictions

“…[19][20][21] Methods for synthesizing fluorinated carboxylic acids are relatively scarce and usually require precious metals or harsh reaction conditions. [22][23][24][25][26][27] Therefore, new synthetic strategies leading to the preparation of these compounds will be soon needed.…”