Tourmaline nano powder was used for the first time in the production of poly(ethylene terephthalate) nanofibers. The polymer chips of poly(ethylene terephthalate) and poly(ethylene terephthalate) containing 3 wt% tourmaline powder were obtained. The electrospun nanofibrous mats were produced from both of the polymer solutions prepared by using the polymer chips. The nanofibrous mats were characterized by using scanning electron microscopy, energy dispersion spectroscopy and Fourier transform infrared spectroscopy. In order to investigate the effect of tourmaline additive in the poly(ethylene terephthalate) nanofibrous mat, water contact angle, electrical conductivity and negative ion releasing measurements were performed on the mats. The incorporation of tourmaline in the nanofibers improved the wettability, electricity transmission and anion emitting property of the poly(ethylene terephthalate) mat.
Keywords poly(ethylene terephthalate), tourmaline, nanofibrous mat, characterizationPolyester fiber based on poly(ethylene terephthalate) (PET) has a wide usage in the textile industry due to its good mechanical properties, low density and chemical resistance. On the other hand, polyester fibers have hydrophobic character due to the lack of polar groups. The hydrophobic nature of fibers causes some disadvantages, such as low moisture regain, high electrostatic behavior, pilling and soiling properties. In order to improve physical, chemical and performance properties of polyester fibers, various modification methods have been performed, such as blending with different additives or polymers and changing the cross-sectional shape. 1-4 In recent years, polyester composite fibers/ nanofibers, including inorganic nanoparticles such as iron, 5 titanium dioxide, 6 montmorillonite, 7 calcium silicate, 8 magnesium hydroxide, 9 silica 10 and perlite, 11 have attracted many researchers' attention for their potential applications in electronic devices, sensors, filters and medical products.Electrospinning is an effective method for the production of nanofibrous mats. The nanofibrous mats have a nanoporous structure, light weight and very high specific surface area, which are also attractive to many potential applications such as in filtration, protective clothing and biomedical engineering. 12,13 Tourmaline (TM) is a natural boron silicate mineral. The general formula of TM is accepted as XY 3 Z 6 (BO 3 ) 3 Si 6 O 18 V 3 W. In this formula, X (Na, Ca, K, vacancy), Y (Li, Mg, Fe 2+ , Fe 3+ , Mn 2+ , Al, Ti 4+ , Cr 3+ ,V 3+ , Zn, vacancy) and Z (Al, Mg, Fe 3+ , Cr 3+ , V 3+ ) sites are cationic elements, and V (OH, O) and W (OH, F, O) sites are anionic elements. 13-15 TM is a polar crystalline material and exhibits spontaneous surface electric fields especially in small granules. 13,16 TM crystals show pyroelectric and piezoelectric characteristics when temperature or pressure conditions change. A TM crystal maintains a pair of electrodes with no supply of external electric energy and can be recognized